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Identify the most likely position for monobromination
Solution: The benzene ring on the right has a deactivating group (acyl) and an activating group (OR). The benzene ring on the left has...
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Starting with benzene, design a synthesis 3-Bromoaniline
Solution: Bromine is ortho/para direction and so is NH2. The two groups are meta to each other in the product. First, we need to do...
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Starting with benzene, design a synthesis of m-bromoethylbenzene
Solution: Bromine is ortho/para directing and ethyl is ortho/para directing as well. However, the groups are meta to one another. We need...
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Draw the reactants that would be used to form this cyclohexene derivative in a Diels-Alder reaction
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Draw the product that could be formed when 1,3-butadiene reacts with (Z)-2-butenedinitrile.
Diels Alder is a ceoncerted one step mechanism where strereochemistry of the diene and dienophile is preserved. The dienophile is cis...
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Write a stepwise reaction mechanism for the reaction shown. Indicate the flow (or rearrangement) of
Write a stepwise reaction mechanism for the reaction shown. Indicate the flow (or rearrangement) of all electrons in each step. A curved...
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Rank the following alkenes in order of stability (1 – 4), with 1 being the least stable
Rank the following alkenes in order of stability (1 – 4), with 1 being the least stable. The more substituted a double bond is (attached...
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Determine the multiplicity of indicated signals in the expected 1H NMR spectrum of the following com
Determine the multiplicity of indicated signals in the expected 1H NMR spectrum of the following compound. Signal Splitting and the (n+1)...
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Is the following alkene E or Z? Show the stepwise procedure.
To figure out E or Z we separate the double bond in two halves. We, then, look at each carbon from the double bond and the two groups it...
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Rank the following in terms of solubility in water.
In order to predict solubility, we need to determine intermolecular forces for the molecules shown. Any molecule that has OH, NH or FH...
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