The reaction X →Y is first-order overall and first-order with respect to the reactant X. The result of doubling the initial concentration of X will be to
A ) double the initial rate.
B) decrease the rate constant of the reaction.
C) shorten the time taken to reach equilibrium.
D) shorten the half-life of the reaction.
E) increase the rate constant of the reaction.
Solution:
First-order with respect to X means that the exponent of [X] in the rate law is 1. This gives the rate law:
Rate=k[X]
This means the rate changes proportionally to the concentration of X. If the concentration of X doubles, the initial rate will also double.
Thus, Choice 1 is correct.
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